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Rafaela Farelo Silva Tenera Marques. Completed the MSc in Chemistry in 2021/02/12 and BSc in Chemistry in 2018/07/12 by Universidade de Lisboa Faculdade de Ciências. She co-supervised 2 course completion of LSc/BSc. She published one article that was also selected for cover story in the Magnetochemistry journal, and she also have a second article accepted to Crystal Growth & Design as first author. She was a member of organizing committee of 2 international events, presented 10 posters in international and national events, had 3 oral presentation in three national events, 1 oral presentation in a seminar in France and participated in other 4 events. She participated in a Master Student Fellow in 1 project and Researcher in 5 projects. She works in the area(s) of Exact Chemical Sciences with emphasis in Inorganic Chemistry. She is skilled in synthesis and characterisation of coordination compounds. During BSc she synthesized and characterized new iron(III) and cobalt(II) complexes with hydrazide derived ligands for their ability to have spin crossover properties. After, during MSc, she synthesized and characterized luminescent spin crossover iron(III) compounds. Now she is a PhD student working on CO2 valorisation with earth abundant metals: From bench to pilot.
Identification

Personal identification

Full name
Rafaela Farelo Silva Tenera Marques

Citation names

  • Rafaela Tenera Marques
  • Rafaela T. Marques
  • R. T. Marques

Author identifiers

Ciência ID
5517-1F0B-410B
ORCID iD
0000-0003-1941-2470

Email addresses

  • rfmarques@gmail.com (Professional)

Knowledge fields

  • Exact Sciences - Chemical Sciences

Languages

Language Speaking Reading Writing Listening Peer-review
Portuguese (Mother tongue)
English Advanced (C1) Upper intermediate (B2) Upper intermediate (B2) Advanced (C1)
French Beginner (A1) Beginner (A1) Beginner (A1) Elementary (A2)
Education
Degree Classification
2022/02/08 - 2026/02/08
Ongoing
Química (Doutoramento)
Universidade de Lisboa Faculdade de Ciências, Portugal
"CO2 valorisation with earth abundant metals: From bench to pilot " (THESIS/DISSERTATION)
2018/09/11 - 2021/02/12
Concluded
Química (Mestrado)
Universidade de Lisboa Faculdade de Ciências, Portugal
"Synthesis and Characterization of Luminescence spin crossover iron(III) compounds" (THESIS/DISSERTATION)
16
2014/09/06 - 2018/07/06
Concluded
Química (Licenciatura)
Universidade de Lisboa Faculdade de Ciências, Portugal
"New iron(III) and cobalt(II) complexes with hydrazide derived ligands" (THESIS/DISSERTATION)
14
Projects

Grant

Designation Funders
2022/02/08 - Current CO2 valorisation with earth abundant metals: From bench to pilot
PTDC/QUI-QIN/0252/2021
PhD Student Fellow
FCiênciasID Associação para a Investigação e Desenvolvimento de Ciências, Portugal
Ongoing
2020 - Current BioISI strategic plan (UIDP/04046/2020)
UIDP/04046/2020
Researcher
Universidade de Lisboa Instituto de Biossistemas e Ciências Integrativas, Portugal
Fundação para a Ciência e a Tecnologia
2020 - Current BioISI strategic plan (UIDB/04046/2020)
UIDB/04046/2020
Researcher
Universidade de Lisboa Instituto de Biossistemas e Ciências Integrativas, Portugal
Fundação para a Ciência e a Tecnologia
2019 - Current CQB strategic plan (UID/MULTI/00612/2019)
UID/MULTI/00612/2019
Researcher
Universidade de Lisboa Centro de Química e Bioquímica, Portugal
2019 - Current BioISI strategic plan (UID/MULTI/04046/2019)
UID/MULTI/04046/2019
Researcher
Universidade de Lisboa Instituto de Biossistemas e Ciências Integrativas, Portugal
2023/01/01 - 2024/01/01 Molecular Magnetic actuators
2022.14998.CBM
Researcher
Universidade de Lisboa Centro de Química Estrutural, Portugal
Ongoing
2020/02/29 - 2020/03/13 Short therm scientific mission: Photoswitching and current flowing in spin crossover iron(III) compounds, Prof. Guillaume Chastanet
ECOST-STSM-CA15128-45944
Master Student Fellow
Institut de Chimie de la Matière Condensée de Bordeaux, France
Concluded
Outputs

Publications

Conference poster
  1. Rafaela T. Marques; Sara Realista; Paulo N. Martinho. "CO2 homogeneous electroreduction using Fe(III) salphen as catalysts". Paper presented in XXIV Meeting of the Portuguese Electrochemical Society, 2023.
  2. Rafaela T. Marques; Sara Realista; Rui G. Santos; Paulo N. Martinho. "CO2 photoreduction using cryptates with Earth abundant metals". Paper presented in 3rd Chem & Biochem Students Meeting, 2023.
  3. Rafaela T. Marques; Sara Realista; Rui G. Santos; Paulo N. Martinho. "CO2 valorisation with earth abundant metals and cryptates". Paper presented in CQE Days, 2023.
  4. Rafaela T. Marques; Sara Realista; Rui G. Santos; Paulo N. Martinho. "CO2 valorisation with earth abundant metals: From bench to pilot". Paper presented in Catalysis Fundamentals and Practice Summer School, 2022.
  5. Rafaela T. Marques; Sara Realista; Paulo N. Martinho. "Homogeneous electroreduction of CO2: Fe(III) salphen as catalysts". Paper presented in CQE Days, 2022.
  6. Rafaela Tenera Marques; Liliana P. Ferreira; Clara S. B. Gomes; Cátia Lopes; Manuel E. Minas da Piedade; Paulo Nuno Martinho. Corresponding author: Rafaela Tenera Marques. "Iron(III) complexes and their solvates: a family of spin crossover compounds". Paper presented in 8th Latin American Symposium on Coordination and Organometallic Chemistry, 2022.
  7. Rafaela T. Marques; Liliana P. Ferreira; Clara S. B. Gomes; Cátia Lopes; Manuel E. Minas da Piedade; Paulo N. Martinho. "Solvate influence on Iron(III) SCO complexes". Paper presented in 7th Pychem - Portuguese Young Chemistry Meeting, 2021.
  8. Reis, Ana R.; Rafaela T. Marques; Liliana P. Ferreira; Saraiva, Marta S.; Martinho, Paulo N.. "Fe(III) spin crossover compounds with luminescent ligands". Paper presented in 7th Portuguese Young Chemists Meeting, Bragança, Portugal (Online), 2021.
  9. Rafaela T. Marques; Frederico F. Martins; Liliana P. Ferreira; Maria J. Calhorda; Paulo N. Martinho. "Symmetric and asymmetric binuclear hydrazide metal complexes: magnetic and spectroscopic studies". Paper presented in SpinOn WorkShop 2018, 2018.
  10. Rafaela T. Marques; Frederico F. Martins; Liliana P. Ferreira; Maria J. Calhorda; Paulo N. Martinho. "Spectroscopic and Magnetic investigation of symmetrical and asymmetrical binuclear hydrazide metal complexes". Paper presented in 3rd Chemistry College meeting "Chemistry at ULisboa" (3ECQUL),, 2018.
  11. Rafaela T. Marques; Frederico F. Martins; Liliana P. Ferreira; Maria J. Calhorda; Paulo N. Martinho. "Magnetic studies on symmetric and asymmetric binuclear hydrazide metal complexes". Paper presented in 6th Young Portuguese Chemists Meeting, 2018.
Journal article
  1. Rafaela T. Marques; Liliana P. Ferreira; Clara S. B. Gomes; Cátia Lopes; Carlos Bernardes; Norid Sarangi; Tia Keyes; Paulo Martinho. "Reversible single-crystal-to-single-crystal transformations in a salEen Fe(III) spin crossover sponge". Crystal Growth & Design 23 5 (2023): 3222-3229. https://doi.org/10.1021/acs.cgd.2c01405.
    Published
  2. Marques, Rafaela T.; Martins, Frederico F.; Bekis, Deniz F.; Vicente, Ana I.; Ferreira, Liliana P.; Gomes, Clara S. B.; Barroso, Sónia; et al. "The Halogen Effect on the Magnetic Behaviour of Dimethylformamide Solvates in [Fe(halide-salEen)2]BPh4". Magnetochemistry 8 12 (2022): 162. http://dx.doi.org/10.3390/magnetochemistry8120162.
    10.3390/magnetochemistry8120162
Activities

Oral presentation

Presentation title Event name
Host (Event location)
2023/12/15 CO2 valorisation with earth abundant metals ICMCB department seminars
(Bordeaux, France)
2023/07/24 Visible light conversion of CO2 using cryptates with Earth abundant metals XXVIII Encontro Nacional da Sociedade Portuguesa de Química
(Aveiro, Portugal)
2022/09/12 Single crystal to single crystal transformations in a mononuclear Fe(III) Shiff base complex Magnetism in Portugal
Núcleo Português de Magnetismo (Porto, Portugal)
2021/07/16 Mononuclear Fe(III) SCO complexes: how do solvates affect the magnetic behavior? XXVII Encontro Nacional da Sociedade Portuguesa de Química
Universidade do Minho (Braga, Portugal)

Supervision

Thesis Title
Role
Degree Subject (Type)
Institution / Organization
2021/04/15 - 2022/07/08 Sensores de compostos heteronucleares de Fe(II) e metais de cunhagem
Co-supervisor
Química (Degree)
Universidade de Lisboa Faculdade de Ciências, Portugal
2019/09/15 - 2020/07/05 Compostos de ferro(III) luminescentes para transição de spin
Co-supervisor
Química (Degree)
Universidade de Lisboa Faculdade de Ciências, Portugal

Event organisation

Event name
Type of event (Role)
Institution / Organization
2022 - 2022 2nd Chem & Biochem Students Meeting (2022/07/15 - 2022/07/15)
Meeting (Member of the Organising Committee)
Universidade de Lisboa Faculdade de Ciências, Portugal
2018/10/01 - 2018/10/02 SpinOn WorkShop 2018 (2018/10/01 - 2018/10/02)
Workshop (Member of the Organising Committee)
Universidade de Lisboa Faculdade de Ciências, Portugal
2015/07/12 - 2015/07/16 19th European Symposium of Organic Chemistry (2015/07/12 - 2015/07/16)
Symposium (Member of the Organising Committee)
Universidade de Lisboa Faculdade de Ciências, Portugal

Event participation

Activity description
Type of event
Event name
Institution / Organization
2022/07/18 - 2022/07/22 Catalysis Fundamentals and Practice Summer School
Other
Catalysis Fundamentals and Practice Summer School
University of Liverpool Department of Chemistry, United Kingdom
2020/09/01 - 2020/09/06 International School of Chemistry - Chemistry for everyday life - Web edition International School of Chemistry - Chemistry for everyday life - Web edition
Università degli Studi di Camerino, Italy
2019/10/09 - 2019/10/09 Synthesis & Catalysis Workshop/Lecture - 10th LAQV-UCIBIO Conference Cycle, in Caparica, Portugal
Workshop
Synthesis & Catalysis Workshop/Lecture - 10th LAQV-UCIBIO Conference Cycle, in Caparica, Portugal
Universidade Nova de Lisboa Faculdade de Ciências e Tecnologia, Portugal
2018/07/29 - 2018/07/29 1st Summer School of Chemistry College, in Lisbon, Portugal
Other
1st Summer School of Chemistry College, in Lisbon, Portugal
Universidade de Lisboa Faculdade de Ciências, Portugal
2017/04/07 - 2017/04/10 V Encontro Nacional de Estudantes de Química
Meeting
V Encontro Nacional de Estudantes de Química
Universidade de Coimbra, Portugal