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Diego is Beamline Scientist on the Core EXAFS beamline B18. Since he joined Diamond Light Source in January 2012, he has also been working for a period in the Industrial Liaison Group as responsible for industrial spectroscopy experiments. Diego studied in his home town of Torino in Italy, acquiring a degree in physics and a PhD in material science. He has spent most of his research career to date focusing on the application of advanced X-ray techniques to the characterisation of materials (including catalysts, micro/nanoporous materials, and transition metal complexes). His particular specialism lies in X-ray Absorption and Emission techniques with an interest in time- resolved experiments. He also developed a good experience in the EXAFS and XANES data analysis and simulations. He is currently involved in research on various topics such as: - study of the active sites and of the chemical reactions in catalysis by combining XAS with Ir or UV-Vis or Raman spectroscopies or by in situ and operando XAS experiments (e.g. Chromocene-based and Phillips-type catalysts for ethylene polymerization and supported copper chloride for oxychlorination reaction); - study of the stability with respect to temperature and of interaction with gases of micro/nanoporous materials by means of operando XAS and quick-EXAFS techniques (e.g. metal organic frameworks and zeolites mainly for gas storage and separation but also for other potential future applications); -study of the electronic structure and excitations of transition metal complexes by means of Resonant XAS/XES and time-resolved XAS (e.g. photoactivatable Ru-polypyridyl complexes promising as anticancer agents for photodynamic therapy or as cage compounds for bioactive ligand release).
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Identificação

Identificação pessoal

Nome completo
Diego Gianolio

Nomes de citação

  • Gianolio, Diego

Identificadores de autor

Ciência ID
7113-A5AE-3485
ORCID iD
0000-0002-0708-4492
Formação
Grau Classificação
2009/01 - 2012/01
Concluído
 PhD in Material Science (Postgraduate Certificate)
Università degli Studi di Torino, Itália
2003/09 - 2008/07
Concluído
 Master Degree in Physics of advanced technologies (Bachelor)
Università degli Studi di Torino, Itália
Percurso profissional

Ciência

Categoria Profissional
Instituição de acolhimento 		Empregador
2012/01 - Atual Investigador (Investigação) Diamond Light Source Ltd, Reino Unido
Produções

Publicações

Artigo em revista
  1. Peng Tang; Hyeon Jeong Lee; Kevin Hurlbutt; Po-Yuan Huang; Sudarshan Narayanan; Chenbo Wang; Diego Gianolio; et al. "Elucidating the Formation and Structural Evolution of Platinum Single-Site Catalysts for the Hydrogen Evolution Reaction". ACS Catalysis (2022): https://doi.org/10.1021/acscatal.1c05958.
    10.1021/acscatal.1c05958
  2. Rosa Arrigo; Takeo Sasaki; June Callison; Diego Gianolio; Manfred Erwin Schuster. "Monitoring dynamics of defects and single Fe atoms in N-functionalized few-layer graphene by in situ temperature programmed scanning transmission electron microscopy". Journal of Energy Chemistry 64 (2022): 520-530. https://doi.org/10.1016/j.jechem.2021.05.005.
    10.1016/j.jechem.2021.05.005
  3. Álvaro García; Tarrick Haynes; María Retuerto; Pilar Ferrer; Laura Pascual; Miguel A. Peña; Mohamed Abdel Salam; et al. "Effect of the Thermal Treatment of Fe/N/C Catalysts for the Oxygen Reduction Reaction Synthesized by Pyrolysis of Covalent Organic Frameworks". Industrial & Engineering Chemistry Research (2021): https://doi.org/10.1021/acs.iecr.1c02841.
    10.1021/acs.iecr.1c02841
  4. Youling Wang; Mikkel J. Larsen; Sergio Rojas; Moulay-Tahar Sougrati; Frédéric Jaouen; Pilar Ferrer; Diego Gianolio; Sandrine Berthon-Fabry. "Influence of the synthesis parameters on the proton exchange membrane fuel cells performance of Fe–N–C aerogel catalysts". Journal of Power Sources 514 (2021): 230561-230561. https://doi.org/10.1016/j.jpowsour.2021.230561.
    10.1016/j.jpowsour.2021.230561
  5. Monik Panchal; June Callison; Vainius Skukauskas; Diego Gianolio; Giannantonio Cibin; Andrew P E York; Manfred E Schuster; et al. "Operando XAFS investigation on the effect of ash deposition on three-way catalyst used in gasoline particulate filters and the effect of the manufacturing process on the catalytic activity". Journal of Physics: Condensed Matter 33 28 (2021): 284001-284001. https://doi.org/10.1088/1361-648X/abfe16.
    10.1088/1361-648X/abfe16
  6. Haoliang Huang; Edward T. C. Hayes; Diego Gianolio; Giannantonio Cibin; Fredrik S. Hage; Quentin M. Ramasse; Andrea E. Russell. "Role of SnO 2 in the Bifunctional Mechanism of CO Oxidation at Pt-SnO 2 Electrocatalysts". ChemElectroChem 8 13 (2021): 2572-2582. https://doi.org/10.1002/celc.202100642.
    10.1002/celc.202100642
  7. Liqun Kang; Bolun Wang; Andreas T. Güntner; Siyuan Xu; Xuhao Wan; Yiyun Liu; Sushila Marlow; et al. "Frontispiece: The Electrophilicity of Surface Carbon Species in the Redox Reactions of CuO-CeO 2 Catalysts". Angewandte Chemie International Edition 60 26 (2021): https://doi.org/10.1002/anie.202182662.
    10.1002/anie.202182662
  8. Liqun Kang; Bolun Wang; Andreas T. Güntner; Siyuan Xu; Xuhao Wan; Yiyun Liu; Sushila Marlow; et al. "Frontispiz: The Electrophilicity of Surface Carbon Species in the Redox Reactions of CuO-CeO 2 Catalysts". Angewandte Chemie 133 26 (2021): https://doi.org/10.1002/ange.202182662.
    10.1002/ange.202182662
  9. Liqun Kang; Bolun Wang; Andreas T. Güntner; Siyuan Xu; Xuhao Wan; Yiyun Liu; Sushila Marlow; et al. "The Electrophilicity of Surface Carbon Species in the Redox Reactions of CuO-CeO 2 Catalysts". Angewandte Chemie International Edition 60 26 (2021): 14420-14428. https://doi.org/10.1002/anie.202102570.
    10.1002/anie.202102570
  10. Liqun Kang; Bolun Wang; Andreas T. Güntner; Siyuan Xu; Xuhao Wan; Yiyun Liu; Sushila Marlow; et al. "The Electrophilicity of Surface Carbon Species in the Redox Reactions of CuO-CeO 2 Catalysts". Angewandte Chemie 133 26 (2021): 14541-14549. https://doi.org/10.1002/ange.202102570.
    10.1002/ange.202102570
  11. Álvaro García; Laura Pascual; Pilar Ferrer; Diego Gianolio; Georg Held; David C. Grinter; Miguel A. Peña; María Retuerto; Sergio Rojas. "Study of the evolution of FeN C and Fe3C species in Fe/N/C catalysts during the oxygen reduction reaction in acid and alkaline electrolyte". Journal of Power Sources 490 (2021): 229487-229487. https://doi.org/10.1016%2Fj.jpowsour.2021.229487.
    10.1016/j.jpowsour.2021.229487
  12. Jianwei Zheng; Simson Wu; Lilin Lu; Chen Huang; Ping-Luen Ho; Angus Kirkland; Tim Sudmeier; et al. "Structural insight into [Fe–S2–Mo] motif in electrochemical reduction of N2 over Fe1-supported molecular MoS2". Chemical Science 12 2 (2021): 688-695. https://doi.org/10.1039%2Fd0sc04575f.
    10.1039/d0sc04575f
  13. Liqun Kang; Bolun Wang; Qiming Bing; Michal Zalibera; Robert Büchel; Ruoyu Xu; Qiming Wang; et al. "Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria". Nature Communications (2020): https://doi.org/10.1038/s41467-020-17852-8.
    10.1038/s41467-020-17852-8
  14. García, Á.; Retuerto, M.; Dominguez, C.; Pascual, L.; Ferrer, P.; Gianolio, D.; Serrano, A.; et al. "Fe doped porous triazine as efficient electrocatalysts for the oxygen reduction reaction in acid electrolyte". Applied Catalysis B: Environmental 264 (2020): http://www.scopus.com/inward/record.url?eid=2-s2.0-85076359164&partnerID=MN8TOARS.
    10.1016/j.apcatb.2019.118507
  15. Arrigo, R.; Gallarati, S.; Schuster, M.E.; Seymour, J.M.; Gianolio, D.; da Silva, I.; Callison, J.; et al. "Influence of Synthesis Conditions on the Structure of Nickel Nanoparticles and their Reactivity in Selective Asymmetric Hydrogenation". ChemCatChem (2020): http://www.scopus.com/inward/record.url?eid=2-s2.0-85078018302&partnerID=MN8TOARS.
    10.1002/cctc.201901955
  16. Catlow, C.R.A.; Wells, P.; Gianolio, D.. "Synchrotron radiation techniques in catalytic science". Physical Chemistry Chemical Physics 22 34 (2020): 18745-18746. http://www.scopus.com/inward/record.url?eid=2-s2.0-85090870349&partnerID=MN8TOARS.
    10.1039/d0cp90186e
  17. Potter, M.E.; Ross, C.P.; Gianolio, D.; Rios, R.; Raja, R.. "Cobalt-containing zeolitic imidazole frameworks for C-H activation using visible-light redox photocatalysis". Catalysis Science and Technology 10 21 (2020): 7262-7269. http://www.scopus.com/inward/record.url?eid=2-s2.0-85096362180&partnerID=MN8TOARS.
    10.1039/d0cy01061h
  18. Kømurcu, M.; Lazzarini, A.; Kaur, G.; Borfecchia, E.; Øien-Ødegaard, S.; Gianolio, D.; Bordiga, S.; Lillerud, K.P.; Olsbye, U.. "Co-catalyst free ethene dimerization over Zr-based metal-organic framework (UiO-67) functionalized with Ni and bipyridine". Catalysis Today (2020): http://www.scopus.com/inward/record.url?eid=2-s2.0-85082819314&partnerID=MN8TOARS.
    10.1016/j.cattod.2020.03.038
  19. Evans, A.; Cummings, M.; Decarolis, D.; Gianolio, D.; Shahid, S.; Law, G.; Attfield, M.; Law, D.; Petit, C.. "Optimisation of Cu+ impregnation of MOF-74 to improve CO/N2 and CO/CO2 separations". RSC Advances 10 9 (2020): 5152-5162. http://www.scopus.com/inward/record.url?eid=2-s2.0-85079244294&partnerID=MN8TOARS.
    10.1039/c9ra10115b
  20. Bowker, M.; Hellier, P.; Decarolis, D.; Gianolio, D.; Mohammed, K.M.H.; Stenner, A.; Huthwelker, T.; Wells, P.P.. "Al-doped Fe2O3as a support for molybdenum oxide methanol oxidation catalysts". Physical Chemistry Chemical Physics 22 34 (2020): 18911-18918. http://www.scopus.com/inward/record.url?eid=2-s2.0-85090715291&partnerID=MN8TOARS.
    10.1039/d0cp01192d
  21. Liu, Y.; Tan, L.; Cibin, G.; Gianolio, D.; Han, S.; Yu, K.; Dove, M.T.; Sapelkin, A.V.. "Analysis of the atomic structure of CdS magic-size clusters by X-ray absorption spectroscopy". Nanoscale 12 37 (2020): 19325-19332. http://www.scopus.com/inward/record.url?eid=2-s2.0-85092681732&partnerID=MN8TOARS.
    10.1039/d0nr05186a
  22. Malta, G.; Kondrat, S.A.; Freakley, S.J.; Morgan, D.J.; Gibson, E.K.; Wells, P.P.; Aramini, M.; et al. "In situ K-edge X-ray absorption spectroscopy of the ligand environment of single-site Au/C catalysts during acetylene hydrochlorination". Chemical Science 11 27 (2020): 7040-7052. http://www.scopus.com/inward/record.url?eid=2-s2.0-85088130323&partnerID=MN8TOARS.
    10.1039/d0sc02152k
  23. María Retuerto; Laura Pascual; Federico Calle-Vallejo; Pilar Ferrer; Diego Gianolio; Amaru González Pereira; Álvaro García; et al. "Na-doped ruthenium perovskite electrocatalysts with improved oxygen evolution activity and durability in acidic media". Nature Communications (2019): https://doi.org/10.1038/s41467-019-09791-w.
    10.1038/s41467-019-09791-w
  24. Titov, K.; Eremin, D.B.; Kashin, A.S.; Boada, R.; Souza, B.E.; Kelley, C.S.; Frogley, M.D.; et al. "OX-1 Metal-Organic Framework Nanosheets as Robust Hosts for Highly Active Catalytic Palladium Species". ACS Sustainable Chemistry and Engineering 7 6 (2019): 5875-5885. http://www.scopus.com/inward/record.url?eid=2-s2.0-85062547551&partnerID=MN8TOARS.
    10.1021/acssuschemeng.8b05843
  25. Sanchez-Cano, C.; Gianolio, D.; Romero-Canelon, I.; Tucoulou, R.; Sadler, P.J.. "Nanofocused synchrotron X-ray absorption studies of the intracellular redox state of an organometallic complex in cancer cells". Chemical Communications 55 49 (2019): 7065-7068. http://www.scopus.com/inward/record.url?eid=2-s2.0-85067305831&partnerID=MN8TOARS.
    10.1039/c9cc01675a
  26. Messinis, A.M.; Luckham, S.L.J.; Wells, P.P.; Gianolio, D.; Gibson, E.K.; O’Brien, H.M.; Sparkes, H.A.; et al. "The highly surprising behaviour of diphosphine ligands in iron-catalysed Negishi cross-coupling". Nature Catalysis 2 2 (2019): 123-133. http://www.scopus.com/inward/record.url?eid=2-s2.0-85059460133&partnerID=MN8TOARS.
    10.1038/s41929-018-0197-z
  27. Cibin, G.; Gianolio, D.; Parry, S.A.; Schoonjans, T.; Moore, O.; Draper, R.; Miller, L.A.; et al. "An open access, integrated XAS data repository at Diamond Light Source". Radiation Physics and Chemistry (2019): http://www.scopus.com/inward/record.url?eid=2-s2.0-85072206176&partnerID=MN8TOARS.
    10.1016/j.radphyschem.2019.108479
  28. Hin, R.C.; Burnham, A.D.; Gianolio, D.; Walter, M.J.; Elliott, T.. "Molybdenum isotope fractionation between Mo4+ and Mo6+ in silicate liquid and metallic Mo". Chemical Geology 504 (2019): 177-189. http://www.scopus.com/inward/record.url?eid=2-s2.0-85057836182&partnerID=MN8TOARS.
    10.1016/j.chemgeo.2018.11.014
  29. Batista De Carvalho, A.L.M.; Mamede, A.P.; Dopplapudi, A.; Garcia Sakai, V.; Doherty, J.; Frogley, M.; Cinque, G.; et al. "Anticancer drug impact on DNA-a study by neutron spectroscopy coupled with synchrotron-based FTIR and EXAFS". Physical Chemistry Chemical Physics 21 8 (2019): 4162-4175. http://www.scopus.com/inward/record.url?eid=2-s2.0-85061869063&partnerID=MN8TOARS.
    10.1039/c8cp05881d
  30. Genovese, C.; Schuster, M. E.; Gibson, E. K.; Gianolio, D.; Posligua, V.; Grau-Crespo, R.; Cibin, G.; et al. "Operando spectroscopy study of the carbon dioxide electro-reduction by iron species on nitrogen-doped carbon". Nature Communications 9 (2018): 12-12. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000426543800002&KeyUID=WOS:000426543800002.
    10.1038/s41467-018-03138-7
  31. Kimber, R. L.; Lewis, E. A.; Parmeggiani, F.; Smith, K.; Bagshaw, H.; Starborg, T.; Joshi, N.; et al. "Biosynthesis and Characterization of Copper Nanoparticles Using Shewanella oneidensis: Application for Click Chemistry". Small 14 10 (2018): 8-8. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000426872300003&KeyUID=WOS:000426872300003.
    10.1002/smll.201703145
  32. Decarolis, D.; Lezcano-Gonzalez, I.; Gianolio, D.; Beale, A.M.. "Effect of Particle Size and Support Type on Pd Catalysts for 1,3-Butadiene Hydrogenation". Topics in Catalysis (2018): 1-13. http://www.scopus.com/inward/record.url?eid=2-s2.0-85040665523&partnerID=MN8TOARS.
    10.1007/s11244-018-0887-4
  33. Callison, J.; Subramanian, N.D.; Rogers, S.M.; Chutia, A.; Gianolio, D.; Catlow, C.R.A.; Wells, P.P.; Dimitratos, N.. "Directed aqueous-phase reforming of glycerol through tailored platinum nanoparticles". Applied Catalysis B: Environmental 238 (2018): 618-628. http://www.scopus.com/inward/record.url?eid=2-s2.0-85050664913&partnerID=MN8TOARS.
    10.1016/j.apcatb.2018.07.008
  34. Rogers, S.M.; Catlow, C.R.A.; Gianolio, D.; Wells, P.P.; Dimitratos, N.. "Supported metal nanoparticles with tailored catalytic properties through sol-immobilisation: Applications for the hydrogenation of nitrophenols". Faraday Discussions 208 (2018): 443-454. http://www.scopus.com/inward/record.url?eid=2-s2.0-85052618395&partnerID=MN8TOARS.
    10.1039/c7fd00216e
  35. Diaz-Moreno, S.; Amboage, M.; Basham, M.; Boada, R.; Bricknell, N.E.; Cibin, G.; Cobb, T.M.; et al. "The Spectroscopy Village at Diamond Light Source". Journal of Synchrotron Radiation 25 4 (2018): 998-1009. http://www.scopus.com/inward/record.url?eid=2-s2.0-85049558543&partnerID=MN8TOARS.
    10.1107/S1600577518006173
  36. Retuerto, M.; Calle-Vallejo, F.; Pascual, L.; Ferrer, P.; García, Á.; Torrero, J.; Gianolio, D.; et al. "Role of lattice oxygen content and Ni geometry in the oxygen evolution activity of the Ba-Ni-O system". Journal of Power Sources 404 (2018): 56-63. http://www.scopus.com/inward/record.url?eid=2-s2.0-85054423782&partnerID=MN8TOARS.
    10.1016/j.jpowsour.2018.09.098
  37. Permien, S.; Neumann, T.; Indris, S.; Neubüser, G.; Kienle, L.; Fiedler, A.; Hansen, A.-L.; et al. "Transition metal cations on the move: Simultaneous: operando X-ray absorption spectroscopy and X-ray diffraction investigations during Li uptake and release of a NiFe2O4/CNT composite". Physical Chemistry Chemical Physics 20 28 (2018): 19129-19141. http://www.scopus.com/inward/record.url?eid=2-s2.0-85050935862&partnerID=MN8TOARS.
    10.1039/c8cp02919a
  38. Brookes, C.; Bowker, M.; Gibson, E.K.; Gianolio, D.; Mohammed, K.M.H.; Parry, S.; Rogers, S.M.; Silverwood, I.P.; Wells, P.P.. "Correction: In situ spectroscopic investigations of MoOx/Fe2O3 catalysts for the selective oxidation of methanol (Catalysis Science and Technology (2016) 6 (722-730) DOI: 10.1039/C5CY01175B)". Catalysis Science and Technology 8 11 (2018): 2998-2998. http://www.scopus.com/inward/record.url?eid=2-s2.0-85048356627&partnerID=MN8TOARS.
    10.1039/c8cy90033g
  39. Raine, E.; Clark, A.H.; Smales, G.; Smith, A.; Gianolio, D.; Li, T.; Zheng, J.; et al. "Synthesis and Characterization of Platinum Nanoparticle Catalysts Capped with Isolated Zinc Species in SBA-15 cChannels: The Wall Effect". ACS Applied Nano Materials 1 12 (2018): 6603-6612. http://www.scopus.com/inward/record.url?eid=2-s2.0-85076250307&partnerID=MN8TOARS.
    10.1021/acsanm.8b01357
  40. Hellier, P.; Wells, P.P.; Gianolio, D.; Bowker, M.. "VOx/Fe2O3Shell–Core Catalysts for the Selective Oxidation of Methanol to Formaldehyde". Topics in Catalysis (2017): 1-8. http://www.scopus.com/inward/record.url?eid=2-s2.0-85032809268&partnerID=MN8TOARS.
    10.1007/s11244-017-0873-2
  41. Marques, M. P. M.; Gianolio, D.; Ramos, S.; de Carvalho, Laeb; Aureliano, M.. "An EXAFS Approach to the Study of Polyoxometalate Protein Interactions: The Case of Decavanadate Actin". Inorganic Chemistry 56 18 (2017): 10893-10903. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000411549400009&KeyUID=WOS:000411549400009.
    10.1021/acs.inorgchem.7b01018
  42. Gibson, E. K.; Crabb, E. M.; Gianolio, D.; Russell, A. E.; Thompsett, D.; Wells, P. P.. "Understanding the role of promoters in catalysis: operando XAFS/DRIFTS study of CeOx/Pt/Al2O3 during CO oxidation". Catalysis Structure & Reactivity 3 1-2 (2017): 5-12. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000411945400002&KeyUID=WOS:000411945400002.
    10.1080/2055074x.2017.1278890
  43. Gibson, E. K.; Stere, C. E.; Curran-McAteer, B.; Jones, W.; Cibin, G.; Gianolio, D.; Goguet, A.; et al. "Probing the Role of a Non-Thermal Plasma (NTP) in the Hybrid NTP Catalytic Oxidation of Methane". Angewandte Chemie-International Edition 56 32 (2017): 9351-9355. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000406385200016&KeyUID=WOS:000406385200016.
    10.1002/anie.201703550
  44. Gallo, E.; Gorelov, E.; Guda, A. A.; Bugaev, A. L.; Bonino, F.; Borfecchia, E.; Ricchiardi, G.; et al. "Effect of Molecular Guest Binding on the d-d Transitions of Ni2+ of CPO-27-Ni: A Combined UV-Vis, Resonant-Valence-to-Core X-ray Emission Spectroscopy, and Theoretical Study". Inorganic Chemistry 56 23 (2017): 14408-14425. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000417342200005&KeyUID=WOS:000417342200005.
    10.1021/acs.inorgchem.7b01471
  45. Dann, E. K.; Gibson, E. K.; Catlow, R. A.; Collier, P.; Erden, T. E.; Gianolio, D.; Hardacre, C.; et al. "Combined In Situ XAFS/DRIFTS Studies of the Evolution of Nanoparticle Structures from Molecular Precursors". Chemistry of Materials 29 17 (2017): 7515-7523. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000410868600056&KeyUID=WOS:000410868600056.
    10.1021/acs.chemmater.7b02552
  46. Gibson, E.K.; Crabb, E.M.; Gianolio, D.; Russell, A.E.; Thompsett, D.; Wells, P.P.. "Understanding the role of promoters in catalysis: operando XAFS/DRIFTS study of CeOx/Pt/Al2O3 during CO oxidation". Catalysis, Structure and Reactivity 3 1-2 (2017): 5-12. http://www.scopus.com/inward/record.url?eid=2-s2.0-85049577532&partnerID=MN8TOARS.
    10.1080/2055074X.2017.1278890
  47. Brookes, Catherine; Bowker, Michael; Gibson, Emma K.; Gianolio, Diego; Mohammed, Khaled M. H.; Parry, Stephen; Rogers, Scott M.; Silverwood, Ian P.; Wells, Peter P.. "In situ spectroscopic investigations of MoOx/Fe2O3 catalysts for the selective oxidation of methanol". Catalysis Science & Technology 6 3 (2016): 722-730. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000369533400017&KeyUID=WOS:000369533400017.
    10.1039/c5cy01175b
  48. Sanchez-Garcia, L.; Bolea, E.; Laborda, F.; Cubel, C.; Ferrer, P.; Gianolio, D.; da Silva, I.; Castillo, J. R.. "Size determination and quantification of engineered cerium oxide nanoparticles by flow field-flow fractionation coupled to inductively coupled plasma mass spectrometry". Journal of chromatography. A 1438 (2016): 205-15. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=MEDLINE&KeyUT=MEDLINE:26903472&KeyUID=MEDLINE:26903472.
    10.1016/j.chroma.2016.02.036
  49. Figueroa, A. I.; Zhang, S. L.; Baker, A. A.; Chalasani, R.; Kohn, A.; Speller, S. C.; Gianolio, D.; et al. "Strain in epitaxial MnSi films on Si(111) in the thick film limit studied by polarization-dependent extended x-ray absorption fine structure". Physical Review B 94 17 (2016): http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000387884700001&KeyUID=WOS:000387884700001.
    10.1103/PhysRevB.94.174107
  50. Cepria, G.; Cordova, W. R.; Cespedes, O.; Sanchez-Garcia, L.; Ferrer, P.; Gianolio, D.; Castillo, J. R.. "Physical and chemical characterization of cerium(IV) oxide nanoparticles". Analytical and Bioanalytical Chemistry 408 24 (2016): 6589-6598. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000382883300007&KeyUID=WOS:000382883300007.
    10.1007/s00216-016-9771-x
  51. Boada, R.; Cibin, G.; Coleman, F.; Diaz-Moreno, S.; Gianolio, D.; Hardacre, C.; Hayama, S.; et al. "Mercury capture on a supported chlorocuprate(II) ionic liquid adsorbent studied using operando synchrotron X-ray absorption spectroscopyt". Dalton Transactions 45 47 (2016): 18946-18953. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000390082900021&KeyUID=WOS:000390082900021.
    10.1039/c6dt03014a
  52. Marques, M. Paula M.; Gianolio, Diego; Cibin, Giannantonio; Tomkinson, John; Parker, Stewart F.; Valero, Rosendo; Pedro Lopes, R.; Batista de Carvalho, Luis A. E.. "A molecular view of cisplatin's mode of action: interplay with DNA bases and acquired resistance". Physical chemistry chemical physics : PCCP 17 7 (2015): 5155-71.
    10.1039/c4cp05183a
  53. de Lima, Juliana Fonseca; Harunsani, Mohammad Hilni; Martin, David James; Kong, Dan; Dunne, Peter W.; Gianolio, Diego; Kashtiban, Reza J.; et al. "Control of chemical state of cerium in doped anatase TiO2 by solvothermal synthesis and its application in photocatalytic water reduction". Journal of Materials Chemistry A 3 18 (2015): 9890-9898. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000353927500067&KeyUID=WOS:000353927500067.
    10.1039/c5ta01474c
  54. Gibson, Emma K.; Beale, Andrew M.; Catlow, C. Richard A.; Chutia, Arunabhiram; Gianolio, Diego; Gould, Anna; Kroner, Anna; et al. "Restructuring of AuPd Nanoparticles Studied by a Combined XAFS/DRIFTS Approach". Chemistry of Materials 27 10 (2015): 3714-3720. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000355382700020&KeyUID=WOS:000355382700020.
    10.1021/acs.chemmater.5b00866
  55. Rogers, Scott M.; Catlow, C. Richard A.; Chan-Thaw, Carine E.; Gianolio, Diego; Gibson, Emma K.; Gould, Anna L.; Jian, Nan; et al. "Tailoring Gold Nanoparticle Characteristics and the Impact on Aqueous-Phase Oxidation of Glycerol". Acs Catalysis 5 7 (2015): 4377-4384. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000357626800057&KeyUID=WOS:000357626800057.
    10.1021/acscatal.5b00754
  56. Corrias, Anna; Conca, Erika; Cibin, Giannantonio; Mountjoy, Gavin; Gianolio, Diego; De Donato, Francesco; Manna, Liberato; Casula, Maria Francesca. "Insights into the Structure of Dot@Rod and Dot@Octapod CdSe@CdS Heterostructures". Journal of Physical Chemistry C 119 28 (2015): 16338-16348. http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000358337700062&KeyUID=WOS:000358337700062.
    10.1021/acs.jpcc.5b04593
  57. Barney, Emma R.; Tang, Zhuoqi; Seddon, Angela; Furniss, David; Sujecki, Slawomir; Benson, Trevor; Neate, Nigel; Gianolio, Diego. "The local environment of Dy3+ in selenium-rich chalcogenide glasses". Rsc Advances 4 80 (2014): 42364-42371.
    10.1039/c4ra07192a
  58. Borfecchia, Elisa; Garino, Claudio; Gianolio, Diego; Salassa, Luca; Gobetto, Roberto; Lamberti, Carlo. "Monitoring excited state dynamics in cis-[Ru(bpy)(2)(py)(2)](2+) by ultrafast synchrotron techniques". Catalysis Today 229 (2014): 34-45.
    10.1016/j.cattod.2013.11.057
  59. Moulki, H.; Faure, C.; Mihelcic, M.; Vuk, A. S.; Svegl, F.; Orel, B.; Campet, G.; et al. "Electrochromic performances of nonstoichiometric NiO thin films". Thin Solid Films 553 (2014): 63-66.
    10.1016/j.tsf.2013.10.154
  60. Gianolio, D.; Borfecchia, E.; Garino, C.; Ruiu, T.; Lamberti, C.; Salassa, L.. "The use of differential EXAFS analysis for the determination of small structural differences between two closely-related ruthenium complexes". Journal of Physics: Conference Series 430 1 (2013): http://www.scopus.com/inward/record.url?eid=2-s2.0-84877315953&partnerID=MN8TOARS.
    10.1088/1742-6596/430/1/012125
  61. Dent, A.J.; Cibin, G.; Ramos, S.; Parry, S.A.; Gianolio, D.; Smith, A.D.; Scott, S.M.; et al. "Performance of B18, the core EXAFS bending magnet beamline at diamond". Journal of Physics: Conference Series 430 1 (2013): http://www.scopus.com/inward/record.url?eid=2-s2.0-84877351004&partnerID=MN8TOARS.
    10.1088/1742-6596/430/1/012023
  62. Mosselmans, J.F.W.; Taylor, R.P.; Quinn, P.D.; Finch, A.A.; Cibin, G.; Gianolio, D.; Sapelkin, A.V.. "A time resolved microfocus XEOL facility at the Diamond Light Source". Journal of Physics: Conference Series 425 PART 18 (2013): http://www.scopus.com/inward/record.url?eid=2-s2.0-84876228635&partnerID=MN8TOARS.
    10.1088/1742-6596/425/18/182009
  63. Romero, Fabio Denis; Burr, Steven J.; McGrady, John E.; Gianolio, Diego; Cibin, Giannantonio; Hayward, Michael A.. "SrFe0.5Ru0.5O2: Square-Planar Ru2+ in an Extended Oxide". Journal of the American Chemical Society 135 5 (2013): 1838-1844.
    10.1021/ja309798e
  64. Gallo, Erik; Bonino, Francesca; Swarbrick, Janine C.; Petrenko, Taras; Piovano, Andrea; Bordiga, Silvia; Gianolio, Diego; et al. "Preference towards Five-Coordination in Ti Silicalite-1 upon Molecular Adsorption". Chemphyschem 14 1 (2013): 79-83.
    10.1002/cphc.201200893
  65. Barzan, Caterina; Gianolio, Diego; Groppo, Elena; Lamberti, Carlo; Monteil, Vincent; Quadrelli, Elsje Alessandra; Bordiga, Silvia. "The Effect of Hydrosilanes on the Active Sites of the Phillips Catalyst: The Secret for In Situ alpha-Olefin Generation". Chemistry-a European Journal 19 51 (2013): 17277-17282.
    10.1002/chem.201303156
  66. Mino, Lorenzo; Gianolio, Diego; Bardelli, Fabrizio; Prestipino, Carmelo; Kumar, E. Senthil; Bellarmine, F.; Ramanjaneyulu, M.; Lamberti, Carlo; Rao, M. S. Ramachandra. "EXAFS and XANES investigation of (Li, Ni) codoped ZnO thin films grown by pulsed laser deposition". Journal of Physics-Condensed Matter 25 38 (2013):
    10.1088/0953-8984/25/38/385402
  67. Gianolio, D.; Vitillo, J.G.; Civalleri, B.; Bordiga, S.; Olsbye, U.; Lillerud, K.P.; Valenzano, L.; Lamberti, C.. "Combined study of structural properties on metal-organic frameworks with same topology but different linkers or metal". Journal of Physics: Conference Series 430 1 (2013): http://www.scopus.com/inward/record.url?eid=2-s2.0-84877357316&partnerID=MN8TOARS.
    10.1088/1742-6596/430/1/012134
  68. Mino, Lorenzo; Agostini, Giovanni; Borfecchia, Elisa; Gianolio, Diego; Piovano, Andrea; Gallo, Erik; Lamberti, Carlo. "Low-dimensional systems investigated by x-ray absorption spectroscopy: a selection of 2D, 1D and 0D cases". Journal of Physics D-Applied Physics 46 42 (2013):
    10.1088/0022-3727/46/42/423001
  69. Lomachenko, Kirill A.; Garino, Claudio; Gallo, Erik; Gianolio, Diego; Gobetto, Roberto; Glatzel, Pieter; Smolentsev, Nikolay; et al. "High energy resolution core-level X-ray spectroscopy for electronic and structural characterization of osmium compounds". Physical chemistry chemical physics : PCCP 15 38 (2013): 16152-9.
    10.1039/c3cp51880a
  70. Borfecchia, Elisa; Garino, Claudio; Salassa, Luca; Ruiu, Tiziana; Gianolio, Diego; Zhang, Xiaoyi; Attenkofer, Klaus; et al. "X-ray transient absorption structural characterization of the (MLCT)-M-3 triplet excited state of cis-[Ru(bpy)(2)(py)(2)](2+)". Dalton Transactions 42 18 (2013): 6564-6571.
    10.1039/c3dt32865a
  71. Romero, Fabio Denis; Gianolio, Diego; Cibin, Giannantonio; Bingham, Paul A.; d'Hollander, Jeanne-Clotilde; Forder, Susan D.; Hayward, Michael A.. "Topochemical Reduction of the Ruddlesden-Popper Phases Sr2Fe0.5Ru0.5O4 and Sr-3(Fe0.5Ru0.5)(2)O-7". Inorganic Chemistry 52 19 (2013): 10920-10928.
    10.1021/ic400930y
  72. Chavan, Sachin; Vitillo, Jenny G.; Gianolio, Diego; Zavorotynska, Olena; Civalleri, Bartolomeo; Jakobsen, Soren; Nilsen, Merete H.; et al. "H-2 storage in isostructural UiO-67 and UiO-66 MOFs". Physical Chemistry Chemical Physics 14 5 (2012): 1614-1626.
    10.1039/c1cp23434j
  73. Rossin, Andrea; Di Credico, Barbara; Giambastiani, Giuliano; Peruzzini, Maurizio; Pescitelli, Gennaro; Reginato, Gianna; Borfecchia, Elisa; et al. "Synthesis, characterization and CO2 uptake of a chiral Co(II) metal-organic framework containing a thiazolidine-based spacer". Journal of Materials Chemistry 22 20 (2012): 10335-10344.
    10.1039/c2jm16236a
  74. Borfecchia, Elisa; Mino, Lorenzo; Gianolio, Diego; Groppo, Chiara; Malaspina, Nadia; Martinez-Criado, Gema; Sans, Juan Angel; et al. "Iron oxidation state in garnet from a subduction setting: a micro-XANES and electron microprobe ("flank method") comparative study". Journal of Analytical Atomic Spectrometry 27 10 (2012): 1725-1733.
    10.1039/c2ja30149k
  75. Jakobsen, Soren; Gianolio, Diego; Wragg, David S.; Nilsen, Merete Hellner; Emerich, Hermann; Bordiga, Silvia; Lamberti, Carlo; et al. "Structural determination of a highly stable metal-organic framework with possible application to interim radioactive waste scavenging: Hf-UiO-66". Physical Review B 86 12 (2012):
    10.1103/PhysRevB.86.125429
  76. Borfecchia, Elisa; Maurelli, Sara; Gianolio, Diego; Groppo, Elena; Chiesa, Mario; Bonino, Francesca; Lamberti, Carlo. "Insights into Adsorption of NH3 on HKUST-1 Metal-Organic Framework: A Multitechnique Approach". Journal of Physical Chemistry C 116 37 (2012): 19839-19850.
    10.1021/jp305756k
  77. Gianolio, D.; Muddada, N. B.; Olsbye, U.; Lamberti, C.. "Doped-CuCl2/Al2O3 catalysts for ethylene oxychlorination: Influence of additives on the nature of active phase and reducibility". Nuclear Instruments & Methods in Physics Research Section B-Beam Interactions with Materials and Atoms 284 (2012): 53-57.
    10.1016/j.nimb.2011.08.004
  78. Muddada, N. B.; Olsbye, U.; Fuglerud, T.; Vidotto, S.; Marsella, A.; Bordiga, S.; Gianolio, D.; Leofanti, G.; Lamberti, C.. "The role of chlorine and additives on the density and strength of Lewis and Bronsted acidic sites of gamma-Al2O3 support used in oxychlorination catalysis: A FTIR study". Journal of Catalysis 284 2 (2011): 236-246.
    10.1016/j.jcat.2011.08.014
  79. Mino, Lorenzo; Gianolio, Diego; Agostini, Giovanni; Piovano, Andrea; Truccato, Marco; Agostino, Angelo; Cagliero, Stefano; et al. "mu-EXAFS, mu-XRF, and mu-PL Characterization of a Multi-Quantum-Well Electroabsorption Modulated Laser Realized via Selective Area Growth". Small 7 7 (2011): 930-938.
    10.1002/smll.201001229
  80. Gianolio, Diego; Groppo, Elena; Vitillo, Jenny G.; Damin, Alessandro; Bordiga, Silvia; Zecchina, Adriano; Lamberti, Carlo. "Direct evidence of adsorption induced Cr-II mobility on the SiO2 surface upon complexation by CO". Chemical Communications 46 6 (2010): 976-978.
    10.1039/b920681g
  81. Salassa, Luca; Ruiu, Tiziana; Garino, Claudio; Pizarro, Ana M.; Bardelli, Fabrizio; Gianolio, Diego; Westendorf, Aron; et al. "EXAFS, DFT, Light-Induced Nucleobase Binding, and Cytotoxicity of the Photoactive Complex cis- Ru(bpy)(2)(CO)Cl (+)". Organometallics 29 24 (2010): 6703-6710.
    10.1021/om100734y
  82. Estephane, J.; Groppo, E.; Vitillo, J. G.; Damin, A.; Gianolio, D.; Lamberti, C.; Bordiga, S.; et al. "A Multitechnique Approach to Spin-Flips for Cp2Cr(II) Chemistry in Confined State". Journal of Physical Chemistry C 114 10 (2010): 4451-4458.
    10.1021/jp907986w
  83. Muddada, N. B.; Olsbye, U.; Caccialupi, L.; Cavani, F.; Leofanti, G.; Gianolio, D.; Bordiga, S.; Lamberti, C.. "Influence of additives in defining the active phase of the ethylene oxychlorination catalyst". Physical Chemistry Chemical Physics 12 21 (2010): 5605-5618.
    10.1039/b926502n
  84. Salassa, Luca; Borfecchia, Elisa; Ruiu, Tiziana; Garino, Claudio; Gianolio, Diego; Gobetto, Roberto; Sadler, Peter J.; et al. "Photo-Induced Pyridine Substitution in cis- Ru(bpy)(2)(py)(2) Cl-2: A Snapshot by Time-Resolved X-ray Solution Scattering". Inorganic Chemistry 49 23 (2010): 11240-11248.
    10.1021/ic102021k
  85. Muddada, N. B.; Olsbye, U.; Leofanti, G.; Gianolio, D.; Bonino, F.; Bordiga, S.; Fuglerud, T.; et al. "Quantification of copper phases, their reducibility and dispersion in doped-CuCl2/Al2O3 catalysts for ethylene oxychlorination". Dalton Transactions 39 36 (2010): 8437-8449.
    10.1039/c0dt00488j
  86. Mino, Lorenzo; Gianolio, Diego; Agostini, Giovanni; Piovano, Andrea; Truccato, Marco; Agostino, Angelo; Cagliero, Stefano; et al. "Structural Characterization of Multi-Quantum Wells in Electroabsorption-Modulated Lasers by using Synchrotron Radiation Micrometer-Beams". Advanced Materials 22 18 (2010): 2050-+.
    10.1002/adma.200903407
  87. Cagliero, Stefano; Piovano, Andrea; Lamberti, Carlo; Khan, Mohammad Mizanur Rahman; Agostino, Angelo; Agostini, Giovanni; Gianolio, Diego; et al. "Synchrotron study of oxygen depletion in a Bi-2212 whisker annealed at 363 K". Journal of Synchrotron Radiation 16 (2009): 813-817.
    10.1107/s0909049509036802
  88. Estephane, Jane; Groppo, Elena; Damin, Alessandro; Vitillo, Jenny G.; Gianolio, Diego; Lamberti, Carlo; Bordiga, Silvia; et al. "Structure and Enhanced Reactivity of Chromocene Carbonyl Confined inside Cavities of NaY Zeolite". Journal of Physical Chemistry C 113 17 (2009): 7305-7315.
    10.1021/jp811240m
  89. Salassa, Luca; Garino, Claudio; Salassa, Giovanni; Nervi, Carlo; Gobetto, Roberto; Lamberti, Carlo; Gianolio, Diego; Bizzarri, Ranieri; Sadler, Peter J.. "Ligand-Selective Photodissociation from Ru(bpy)(4AP)(4) (2+): a Spectroscopic and Computational Study". Inorganic Chemistry 48 4 (2009): 1469-1481.
    10.1021/ic8015436
  90. Cagliero, S.; Piovano, A.; Lamberti, C.; Rahman Khan, M.M.; Agostino, A.; Agostini, G.; Gianolio, D.; et al. "Synchrotron study of oxygen depletion in a Bi-2212 whisker annealed at 363 K". Journal of Synchrotron Radiation 16 6 (2009): 813-817. http://www.scopus.com/inward/record.url?eid=2-s2.0-69849106491&partnerID=MN8TOARS.
    10.1107/S0909049509036802
Capítulo de livro
  1. Gianolio, D.; Borfecchia, E.; Garino, C.; Ruiu, T.; Lamberti, C.; Salassa, L.. "The Use of Differential EXAFS Analysis for the determination of Small Structural Differences between two closely-related Ruthenium Complexes". editado por Wu, Z. Y.. 2013.
    Unsp 01212510.1088/1742-6596/430/1/012125
  2. Dent, A. J.; Cibin, G.; Ramos, S.; Parry, S. A.; Gianolio, D.; Smith, A. D.; Scott, S. M.; et al. "Performance of B18, the Core EXAFS Bending Magnet beamline at Diamond". editado por Wu, Z. Y.. 2013.
    Unsp 01202310.1088/1742-6596/430/1/012023
  3. Mosselmans, J. F. W.; Taylor, R. P.; Quinn, P. D.; Finch, A. A.; Cibin, G.; Gianolio, D.; Sapelkin, A. V.. "A time resolved microfocus XEOL facility at the Diamond Light Source". editado por Susini, J.; Dumas, P.. 2013.
    Unsp 18200910.1088/1742-6596/425/18/182009
  4. Gianolio, D.; Vitillo, J. G.; Civalleri, B.; Bordiga, S.; Olsbye, U.; Lillerud, K. P.; Valenzano, L.; Lamberti, C.. "Combined study of structural properties on metal-organic frameworks with same topology but different linkers or metal". editado por Wu, Z. Y.. 2013.
    Unsp 01213410.1088/1742-6596/430/1/012134
  5. Salassa, Luca; Gianolio, Diego; Garino, Claudio; Salassa, Giovanni; Borfecchia, Elisa; Ruiu, Tiziana; Nervi, Carlo; et al. "Structure of Ru(bpy)(n)(AP)((6-2n)) (2+) homogeneous complexes: DFT calculation vs. EXAFS". editado por DiCicco, A.; Filipponi, A.. 2009.
    10.1088/1742-6596/190/1/012141
  6. Gianolio, D.; Groppo, E.; Estephane, J.; Prestipino, C.; Nikitenko, S.; Zecchina, A.; Bordiga, S.; et al. "Formation and reactivity of Cr(II) carbonyls hosted in polar and non polar supports". editado por DiCicco, A.; Filipponi, A.. 2009.
    10.1088/1742-6596/190/1/012140
Livro
  1. Bonino, F.; Groppo, E.; Prestipino, C.; Agostini, G.; Piovano, A.; Gianolio, D.; Mino, L.; Gallo, E.; Lamberti, C.. Catalyst characterization by xas and xes spectroscopies: In situ and operando experiments. 2015.
    10.1007/978-3-642-55315-8_28
  2. Gianolio, D.. How to Start an XAS Experiment. 2015.
    10.1002/9781118844243.ch5
  3. Borfecchia, E.; Agostini, G.; Bordiga, S.; Groppo, E.; Garino, C.; Gobetto, R.; Agostino, A.; et al. Structural and electronic characterization of nanosized inorganic materials by X-ray absorption spectroscopies. 2013.
    10.1515/9783110306873.93